Iterative approach to polyketide-type structures: stereoselective synthesis of 1,3-polyols utilizing the catalytic asymmetric Overman esterification.
نویسندگان
چکیده
An iterative systematic approach to the 1,3-polyol motif has been developed to provide access to all possible stereoisomers by utilizing the catalytic asymmetric Overman esterification for the construction of all stereogenic centres.
منابع مشابه
Synthesis of some Polyol Esters and Diesters Catalyzed with SnO2 and Nano-SnO2
Esterification reactions of some polyols and diols were investigated in the presence of SnO2 and nano-SnO2 and the results were compared with the catalyst-free conditions. High conversions were obtained for most of the reactions in the presence of SnO2 and nano-SnO2 which shows the high catalytic activity of SnO2 and nano-SnO2</sub...
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ورودعنوان ژورنال:
- Chemical communications
دوره 40 شماره
صفحات -
تاریخ انتشار 2007